Femtosecond Transient Absorption Studies of Simple Polyenes in Solution
نویسندگان
چکیده
منابع مشابه
Femtosecond transient absorption, Raman, and electrochemistry studies of tetrasulfonated copper phthalocyanine in water solutions.
Ultrafast time-resolved electronic spectra of the primary events induced in the copper tetrasulfonated phthalocyanine Cu(tsPc)4-) in aqueous solution has been measured by femtosecond pump-probe transient absorption spectroscopy. The primary events initiated by the absorption of a photon occurring within the femtosecond time scale are discussed on the basis of the electron transfer mechanism bet...
متن کاملSimple nanosecond to minutes transient absorption spectrophotometer.
We built a transient absorption spectrophotometer that can determine transient absorption spectral changes that occur at times as fast as approximately 200 ns and as slow as a minute. The transient absorption can be induced by a temperature-jump (T-jump) or by optical pumping from the deep ultraviolet (UV) to the infrared (IR) by use of single ns Nd:YAG laser pulses. Our use of a fiber-optic sp...
متن کاملFemtosecond pump-probe studies of nitrosyl chloride photochemistry in solution.
We present a femtosecond pump-probe study of the primary events of nitrosyl chloride (ClNO) photochemistry in solution. Following 266 nm photolysis, the resulting evolution in optical density is measured for ClNO dissolved in acetonitrile, chloroform, and dichloromethane. The results demonstrate that photolysis results in the production of a photoproduct that has an absorption band maximum at 2...
متن کاملModeling transient absorption and thermal conductivity in a simple nanofluid.
Molecular dynamics simulations are used to simulate the thermal properties of a model fluid containing nanoparticles (nanofluid). By modeling transient absorption experiments, we show that they provide a reliable determination of interfacial resistance between the particle and the fluid. The flexibility of molecular simulation allows us to consider separately the effect of confinement, particle...
متن کاملFemtosecond time-resolved absorption spectroscopy of astaxanthin in solution and in alpha-crustacyanin.
Steady-state absorption and femtosecond time-resolved spectroscopic studies have been carried out on astaxanthin dissolved in CS2, methanol, and acetonitrile, and in purified alpha-crustacyanin. The spectra of the S0 --> S2 and S1 --> S(n) transitions were found to be similarly dependent on solvent environment. The dynamics of the excited-state decay processes were analyzed with both single wav...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Laser Chemistry
سال: 1999
ISSN: 0278-6273,1476-3516
DOI: 10.1155/1999/80507